Hm... doing the villains is hard because they aren't as fleshed out as the heroes. I always thought Gaston had the flaws of a Leo, but Aries is a good fit too. Mother Gothel as Cancer I love. :) Not sure about the rest, hm...

Frollo I always thought of as a Scorpio. Scar as Capricorn - yes! And I can see Shan Yu as Leo. Clayton... I don't even remember him having much personality other than ruthless greediness. I'll have to think about the other villains for a bit. If you have any rationales, I'd love to hear them.

Enchanted characters: Robert as Virgo is really good. :)